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PRO-SEAL 60W [Part B]
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MATERIAL SAFETY DATA SHEET Product Name: PRO-SEAL 60W, Part B SECTION 1: IDENTIFICATION MANUFACTURER: LiquidConcrete, Inc. ADDRESS: P.O Box 16782, Seattle, WA 98116 PHONE: 1 (800) 201-9300 CHEMICAL NAME: Mixture COMMON NAME: PRO-SEAL 60W, Part B CHEMICAL FAMILY: MANNICH BASE ADDUCT SECTION 2: HAZARDOUS CHEMICALS H.M.I.S. RATING Health Flammability Reactivity 1 1 0 APPLICABLE EXPOSURE LIMITS CHEMICAL NAME/CAS # Water / 7732-18-5 Adduct T/S % >30 <70 PEL-WISHA/OSHA N/A N/A TLV-ACGIH N/A N/A OTHER N/A N/A This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910 1200). In addition, other substances non-hazardous per this OSHA standard may be listed. When proprietary ingredient shows, the identity may be made available as provided in this standard. No lead or chromium pigments are used. N/E = Not Established T/S = Trade Secret SECTION 3: HEALTH HAZARDS ROUTES OF EXPOSURE: Eye Contact Skin Contact Ingestion Inhalation EXPOSURE STANDARDS: No exposure standards established for the product. Maintain contaminant concentrations in the Revision Date: April 30, 2007 Page 1 of 6 Effective Date: April 30, 2007 MATERIAL SAFETY DATA SHEET Product Name: PRO-SEAL 60W, Part B workplace at the lowest feasible levels. HEALTH HAZARDS: Mild eye irritant. No corneal injury likely. May cause allergic skin reaction in susceptible individuals. Prolonged exposure not likely to cause significant irritation. Repeated exposure may cause skin irritation. A single prolonged exposure is not likely to result in the material being absorbed through the skin in harmful amounts. MEDICAL conditions generally aggravated by exposure: None known CARCINOGENS UNDER OSHA, ACGIH, IARC, OTHER: This product contains no carcinogens in concentrations of 0.1 percent or greater. SECTION 4: FIRST AID EYE CONTACT: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. SKIN CONTACT: Wash affected area with soap and water. Wash clothing before reuse. INHALATION: Move victim to fresh air if effect occurs. INGESTION: Low in toxicity. NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgement of the physician in response to the reactions of the patient. SECTION 5: FIRE AND EXPLOSION DATA FLASH POINT (closed cup): 140°C (219°F) Not applicable Not applicable UPPER EXPLOSION LIMIT (UEL) LOWER EXPLOSION LIMIT (LEL) EXTINGUISHING MEDIA Ignition will give rise to a class B fire. In case of fire use water spray, alcohol foam. In case of small fire use carbon dioxide (CO2), dry chemical. Revision Date: April 30, 2007 Page 2 of 6 Effective Date: April 30, 2007 MATERIAL SAFETY DATA SHEET Product Name: PRO-SEAL 60W, Part B SPECIAL FIRE FIGHTING PROCEDURES Firefighters should wear self-contained breathing apparatus. SECTION 6: ACCIDENTAL RELEASE MEASURES CONTAINMENT TECHNIQUES (Removal of ignition sources, diking etc.) Stop the leak if possible. Ventilate the space involved. Shut off or remove all ignition sources. Construct a dike to prevent spreading (includes molten liquids until they freeze). CLEAN-UP PROCEDURES: If recovery is not feasible, admix with dry soil, sand or non-reactive absorbent and place in an appropriate chemical waste container. Transfer to containers by suction, preparatory for later disposal. Place in metal containers for recovery or disposal. Flush area with water spray. Clean-up personnel must be equipped with self contained breathing apparatus and butyl rubber protective clothing. For large spills, recover spilled material with a vacuum truck. SECTION 7: HANDLING AND STORAGE STORAGE: Keep in cool, dry, ventilated storage and in closed containers. Do not store in reactive metal containers. HANDLING: Avoid contact with skin or eyes. When handling, do not eat, drink, or smoke. OTHER PRECAUTIONS: Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations (e.g. OSHA). SECTION 8: PERSONAL PROTECTION AND EXPOSURE CONTROLS EYE PROTECTION: Chemical safety glasses HAND PROTECTION: Polyvinyl chloride gloves. RESPIRATORY PROTECTION: Not required under normal conditions in a well-ventilated workplace. An organic vapor respirator NIOSHA approved for organic vapors is recommended under emergency conditions. PROTECTIVE CLOTHING AND ENGINEERING CONTROLS: No specific recommendations. SECTION 9: TYPICAL PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM: Liquid COLOR: Varies VAPOR PRESSURE (mm Hg at 21°C (70°F): 17.17 VAPOR DENSIT: (Air=1) Not applicable BOILING POINT: > 100°C (> 212°F) Revision Date: April 30, 2007 Page 3 of 6 Effective Date: April 30, 2007 MATERIAL SAFETY DATA SHEET Product Name: PRO-SEAL 60W, Part B SOLUBILITY IN WATER: Slight (0.1-1%) SPECIFIC GRAVITY (Water=1): 1.08 pH: Alkaline ODOR: N/A SECTION 10: STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable at ambient temperatures. CONDITIONS TO AVOID ( if unstable): Not applicable INCOMPATIBILITY (Materials to avoid): Mineral acids (i.e. sulfuric, phosphoric, etc.). Alkalis (i.e. Sodium or Potassium Hydroxide, etc.) Organic acids (i.e. acetic acid, citric acid, etc.) Oxidizing Agents (i.e. perchlorates, nitrates, etc.) Sodium or Calcium Hypochlorite. Product slowly corrodes copper, aluminum, zinc and galvanized surfaces. Reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion. A reaction with accompanying large heat release occurs when the product is mixed with acids. Heat generated may be sufficient to cause vigorous boiling creating a hazard due to splashing or splattering of hot material. HAZARDOUS DECOMPOSITION PRODUCTS: (from burning, heating or reaction with other materials): Nitrogen oxide can react with water vapors to form corrosive nitric acid (TLV=2 ppm). Carbon monoxide/dioxide in a fire. Ammonia when heated. Nitrogen Oxides in a fire. Irritating and toxic fumes at elevated temperatures. Nitric acid in a fire. The oxides of nitrogen gases (except nitrous oxide) emitted on decomposition are highly toxic. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11: TOXICOLOGICAL PROPERTIES ACUTE ORAL TOXICITY: (LD50, RAT): No data ACUTE DERMAL TOXICITY ( LD50, RABBIT): No data ACUTE INHALATION TOXICITY (LC50, RAT): No data Revision Date: April 30, 2007 Page 4 of 6 Effective Date: April 30, 2007 MATERIAL SAFETY DATA SHEET Product Name: PRO-SEAL 60W, Part B CHRONIC/SUBCHRONIC DATA: Except for skin sensitization, repeated exposures to low molecular weight epoxies of the type are not anticipated to cause any significant adverse effects. A poorly characterized sample of low molecular weight epoxy resin of the type has been reported to SECTION 12: ECOLOGICAL INFORMATION N/A SECTION 13: DISPOSAL INFORMATION WASTE DISPOSAL: Comply with all Federal, State and Local Regulations. SECTION 14: TRANSPORT INFORMATION DOT and ICAO/IATA NON-BULK SHIPPING NAME – RESIN COMPOUND – Not DOT or IATA Regulated. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS TOXIC SUBSTANCES CONTROL ACT (TSCA): The components of this product are contained on the chemical substance inventory list. COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION and LIABILITY ACT OF 1980 (CERCLA).: Requires notification of the National Response Center of release of quantities of Hazardous Substances equal to or greater than the reportable quantities (RQ’s) in 40 CFR 302.4. There are no components present in this product at a level which could require reporting under the statute. SUPERFUND AMENDMENTS and REAUTHORIZATION ACT OF 1986 (SARA) TITLE III: Sections 301-304 require emergency planning based on Threshold Planning Quantities (TPQ’s) and release reporting based on Reportable Quantities (RQ’s) in 40 CFR 355. There are no components present in this product at a level which could require reporting under the statute. Sections 311-312 require products be reviewed and applicable EPA Hazard Definitions be identified and made known. EPA HAZARD CLASSIFICATIONS: ACUTE NO CHRONIC NO FIRE NO PRESSURE NO REACTIVE NO Section 313 requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). This information must be included in all MSDS’s that are copied and distributed for this material. There are no components present in this product at a level which could require reporting under the statute. STATE REGULATIONS Revision Date: April 30, 2007 Page 5 of 6 Effective Date: April 30, 2007 MATERIAL SAFETY DATA SHEET Product Name: PRO-SEAL 60W, Part B PROPOSITION 65 SUBSTANCES (component(s) known to the State of California to cause cancer and/or reproductive toxicity and subject to warning and discharge requirements under the “Safe Drinking Water and Toxic Enforcement Act of 1986"): None NEW JERSEY TRADE SECRET REGISTRY NUMBER(S): None INTERNATIONAL REGULATIONS CANADA DSL: Included on Inventory WHMIS Hazard Classification: None WHMIS Trade Secret Registry Number(s): None WHMIS SYMBOLS: None European Economic Community (EEC) Einecs/Elincs Master Inventory: Included on Inventory EEC Risk (R) Phrases: There are no known health hazards SECTION 16: OTHER INFORMATION DISCLAIMER: The information contained herein is based on data believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable regarding all current regulations. Revision Date: April 30, 2007 Page 6 of 6 Effective Date: April 30, 2007